A Quantum Cascade Laser-Based Optical Sensor for Continuous Monitoring of Environmental Methane in Dunkirk (France)

Autor: Rabih Maamary, Xiaojuan Cui, Eric Fertein, Patrick Augustin, Marc Fourmentin, Dorothée Dewaele, Fabrice Cazier, Laurence Guinet, Weidong Chen
Jazyk: angličtina
Rok vydání: 2016
Předmět:
Zdroj: Sensors, Vol 16, Iss 2, p 224 (2016)
Druh dokumentu: article
ISSN: 1424-8220
DOI: 10.3390/s16020224
Popis: A room-temperature continuous-wave (CW) quantum cascade laser (QCL)-based methane (CH4) sensor operating in the mid-infrared near 8 μm was developed for continuous measurement of CH4 concentrations in ambient air. The well-isolated absorption line (7F2,4 ← 8F1,2) of the ν4 fundamental band of CH4 located at 1255.0004 cm−1 was used for optical measurement of CH4 concentration by direct absorption in a White-type multipass cell with an effective path-length of 175 m. A 1σ (SNR = 1) detection limit of 33.3 ppb in 218 s was achieved with a measurement precision of 1.13%. The developed sensor was deployed in a campaign of measurements of time series CH4 concentration on a site near a suburban traffic road in Dunkirk (France) from 9th to 22nd January 2013. An episode of high CH4 concentration of up to ~3 ppm has been observed and analyzed with the help of meteorological parameters combined with back trajectory calculation using the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model of NOAA.
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