Bis(1H-benzimidazole-κN3)bis[2-(naphthalen-1-yl)acetato-κ2O,O′]manganese(II) monohydrate
| Autor: | Li-Ping Wang, Shu-An Li, Zhen-Ming Zhang, Fu-Jun Yin |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 3, Pp m328-m328 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812007441 |
| Popis: | In the title compound, [Mn(C12H9O2)2(C7H6N2)2]·H2O, the MnII ion is located on a twofold rotation axis and six-coordinated, displaying a distorted MnN2O4 octahedral geometry. The crystal packing is stabilized by N—H...O hydrogen bonds, which give rise to a one-dimensional structure along [001], and π–π interactions between the imidazole rings and between the benzene rings of the 2-(naphthalen-1-yl)acetate ligands [centroid–centroid distances = 3.761 (3) and 3.728 (4) Å]. The contribution of the electron density associated with the disordered water molecules was not considerd in the final structure model. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|