Microstructure-Properties of Dynamically Vulcanized Mengkuang Leaf Fibre/Ethylene Vinyl Acetate/Natural Rubber Thermoplastic Elastomer Composites
| Autor: | Faiezah Hashim, Indra Surya, Arjulizan Rusli, Hanafi Ismail |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | BioResources, Vol 17, Iss 4, Pp 6036-6055 (2022) |
| Druh dokumentu: | article |
| ISSN: | 1930-2126 47018089 |
| Popis: | Thermoplastic elastomer composites based on ethylene vinyl acetate (EVA), natural rubber (NR), and Mengkuang leaf fibre were prepared using the sulfur and peroxide vulcanization systems. Different curing systems and fibre loadings affecting the processing torque, tensile, thermal, and morphology of the composites were investigated. Addition of Mengkuang leaf fibre resulted in poor fibre dispersion and agglomeration in the matrix, which may have affected the efficiency of stress transfer and thus could explain a decline in tensile and thermal properties. Composites with dynamic vulcanization showed a rougher surface that might be due to the presence of crosslinking, which requires more force to fail. The increase in stabilization torque for the composites with dynamic vulcanization was observed due to the addition of curing agents, which implies some changes at the molecular level due to crosslinking. Tensile properties of Mengkuang leaf fibre filled EVA/NR composites indicated that the tensile strength, elongation at break, and Young’s modulus of the peroxide cure system were higher than the sulfur cure system and unvulcanised composites. The sulphur cure system showed better resistance towards thermal degradation compared to the peroxide cure system. This was attributed to dicumyl peroxide (DCP), which degrades the polymer chain or the composites at high temperature. |
| Databáze: | Directory of Open Access Journals |
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