The channel structure of trithallium pentaantimonate(V), Tl3Sb5O14
| Autor: | Paul Sicher, Berthold Stöger |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 4, Pp 414-417 (2022) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989022002869 |
| Popis: | Single crystals of Tl3Sb5O14 were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K3Sb5O14, Rb3Sb5O14 and Cs3Sb5O14 analogues with orthorhombic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO6] octahedra, which are linked via edges and corners into a triperiodic network. The Tl+ ions are located in distinct channels of the network extending along [010] and [001]. |
| Databáze: | Directory of Open Access Journals |
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