Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Autor: Ioana Georgeta Grosu, Christiane Berghof, Peter Lönnecke, Luminita Silaghi-Dumitrescu, Evamarie Hey-Hawkins
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Molecules, Vol 20, Iss 5, Pp 8020-8032 (2015)
Druh dokumentu: article
ISSN: 1420-3049
20058020
DOI: 10.3390/molecules20058020
Popis: Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.
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