Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-phenylbenzoate) 2.66-hydrate
| Autor: | José A. Fernandes, Ana I. Ramos, Patrícia Silva, Susana S. Braga, Paulo Ribeiro-Claro, João Rocha, Filipe A. Almeida Paz |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 6, Pp m626-m627 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810016223 |
| Popis: | In the title complex, [Cu(C2H8N2)2(H2O)2](C13H9O2)2·2.66H2O, the CuII centre (located at an inversion centre) is coordinated by two bidentate ethylenediamine (en) ligands and two water O atoms in a typical Jahn–Teller distorted octahedral geometry. The amino groups and the water molecules are disordered over two distinct crystallographic positions with occupancies of 1/3 and 2/3. In the crystal, the cations and anions are disposed in alternating layers. One of the water molecules of crystallization is disordered and the other has a fractional occupation. In the 2/3 occupancy component, water molecules are organized into a chain composed of hexameric units interconnected by carboxylate bridges. |
| Databáze: | Directory of Open Access Journals |
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