Sensitivity-Enhanced, Room-Temperature Detection of NH3 with Alkalized Ti3C2Tx MXene
| Autor: | Yi Tan, Jinxia Xu, Qiliang Li, Wanting Zhang, Chong Lu, Xingjuan Song, Lingyun Liu, Ying Chen |
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| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Nanomaterials, Vol 14, Iss 8, p 680 (2024) |
| Druh dokumentu: | article |
| ISSN: | 14080680 2079-4991 |
| DOI: | 10.3390/nano14080680 |
| Popis: | A layered Ti3C2Tx MXene structure was prepared by etching MAX-phase Ti3AlC2 with hydro-fluoric acid (HF), followed by alkalization in sodium hydroxide (NaOH) solutions of varying concentrations and for varying durations. Compared to sensors utilizing unalkalized Ti3C2Tx, those employing alkalized Ti3C2Tx MXene exhibited enhanced sensitivity for NH3 detection at room temperature and a relative humidity of 40%. Both the concentration of NaOH and duration of alkalization significantly influenced sensor performance. Among the tested conditions, Ti3C2Tx MXene alkalized with a 5 M NaOH solution for 12 h exhibited optimal performance, with high response values of 100.3% and a rapid response/recovery time of 73 s and 38 s, respectively. The improved sensitivity of NH3 detection can be attributed to the heightened NH3 adsorption capability of oxygen-rich terminals obtained through the alkalization treatment. This is consistent with the observed increase in the ratio of oxygen to fluorine atoms on the surface terminations of the alkalization-treated Ti3C2Tx. These findings suggest that the gas-sensing characteristics of Ti3C2Tx MXene can be finely tuned and optimized through a carefully tailored alkalization process, offering a viable approach to realizing high-performance Ti3C2Tx MXene gas sensors, particularly for NH3 sensing applications. |
| Databáze: | Directory of Open Access Journals |
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