| Autor: |
Ghada Ayoub, Mihails Arhangelskis, Xuan Zhang, Florencia Son, Timur Islamoglu, Tomislav Friščić, Omar K. Farha |
| Jazyk: |
angličtina |
| Rok vydání: |
2019 |
| Předmět: |
|
| Zdroj: |
Beilstein Journal of Nanotechnology, Vol 10, Iss 1, Pp 2422-2427 (2019) |
| Druh dokumentu: |
article |
| ISSN: |
2190-4286 |
| DOI: |
10.3762/bjnano.10.232 |
| Popis: |
We demonstrate a microporous metal–organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes’ half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal–organic framework linker permits modification of its photoactive behavior. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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