Novel one-pot microwave synthesis of maleic anhydride based mineral scale inhibitors and their application

Autor: Yousef M. Al-Roomi, Kaneez F. Hussain
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Journal of King Saud University: Engineering Sciences, Vol 35, Iss 7, Pp 442-449 (2023)
Druh dokumentu: article
ISSN: 1018-3639
DOI: 10.1016/j.jksues.2021.07.008
Popis: This paper presents our research efforts in the discovery of pioneering synthetic routes and designing low molecular-weight maleic-anhydride (MA) homopolymers and MA-n-octyl acrylamide (AAO) copolymers (YMR-series) and their application as scale inhibitors for mineral scales. Hence, the solvent-free, eco-friendly, rapid microwave-assisted method has been developed for the first time to synthesize these antiscalants with higher yield and better efficiency. The inhibition ability on the CaSO4 and CaCO3 scale is 100 % with a 3 ppm dosage level at pH 10.45 and temperature 70 °C.Morphological changes of the CaCO3 and CaSO4 scales due to the strong inhibition action of YMR-series polymers have been studied by scanning electronic microscopy (SEM) and X-ray powder diffraction (XRD) analysis. It is also observed that the anti-scaling effect of the polymers greatly depends on the molecular weight, while MA copolymers show better inhibition efficiency compared to MA homopolymers.
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