Arene C–H borylation strategy enabled by a non-classical boron cluster-based electrophile

Autor: Sangmin Kim, Joseph W. Treacy, Yessica A. Nelson, Jordan A. M. Gonzalez, Milan Gembicky, K. N. Houk, Alexander M. Spokoyny
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Nature Communications, Vol 14, Iss 1, Pp 1-9 (2023)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-023-37258-6
Popis: Electrophilic borylation of sterically hindered arenes is a challenging transformation. Here, authors report a metal-free electrophilic C–H borylation of hindered arenes using a boron cluster reagent producing valuable aryl boronic esters.
Databáze: Directory of Open Access Journals
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