A comparative study of hydroxyethylcellulose‐based solid polymer electrolytes for solid state Zn batteries

Autor: Amandine Brige, Martina Olsson, Shizhao Xiong, Aleksandar Matic
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Nano Select, Vol 4, Iss 1, Pp 102-111 (2023)
Druh dokumentu: article
ISSN: 2688-4011
20220022
DOI: 10.1002/nano.202200221
Popis: Abstract Rechargeable zinc metal batteries are greener and safer alternative to lithium batteries, but they suffer from poor reversibility due to growth of zinc dendrites and water splitting reactions of aqueous electrolytes. One strategy to overcome these drawbacks is replacing aqueous electrolyte with solid polymer electrolyte (SPE). In this work, we examine the possibility of fabricating solid electrolyte from a bio‐based polymer, hydroxyethylcellulose (HEC), with the aim to further increase the sustainability of zinc batteries. Various types of zinc salts, drying procedures and the salt concentrations are investigated for their impact on the ionic conductivity, structure, and phase behavior of as‐prepared polymer electrolytes. It is found that HEC has a good film‐forming ability compared with commonly used poly(ethylene oxide) but its low salt‐dissociation capability leads to an ionic conductivity of 10−6 S cm−1 even at the elevated temperature of 110°C, hindering the possibility of solely utilizing HEC as matrix of solid electrolyte. Our results suggest that introducing a new polymer with higher salt‐dissociation capability or lower glass transition temperature into the HEC matrix can be a reliable way to build solid polymer electrolytes with sufficient ionic conductivity and good mechanical property for future zinc batteries.
Databáze: Directory of Open Access Journals
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