Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection

Autor: Daofu Yuan, Yin Huang, Wentao Chen, Hailin Zhao, Shengrui Yu, Chang Luo, Yuxin Tan, Siwen Wang, Xingan Wang, Zhigang Sun, Xueming Yang
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-020-17381-4
Popis: The geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental evidence and insight into its origin.
Databáze: Directory of Open Access Journals