Reactions of nitroxides 15. Cinnamates bearing a nitroxyl moiety synthesized using a Mizoroki–Heck cross-coupling reaction

Autor:	Jerzy Zakrzewski, Bogumiła Huras
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	4-acryloyloxy-2 2 6 6-tetramethylpiperidine-1-oxyl cinnamates Mizoroki–Heck cross-coupling reaction nitroxides Science Organic chemistry QD241-441
Zdroj:	Beilstein Journal of Organic Chemistry, Vol 11, Iss 1, Pp 1155-1162 (2015)
Druh dokumentu:	article
ISSN:	1860-5397
DOI:	10.3762/bjoc.11.130
Popis:	Cinnamic acid derivatives bearing a nitroxyl moiety (2,2,6,6-tetramethyl-1-oxyl-4-piperidyl 3-E-aryl acrylates) were synthesized in 30–100% yield using a Mizoroki–Heck cross-coupling reaction between 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl and iodobenzene derivatives in the presence of palladium(II) acetate coordinated with a tri(o-tolyl)phosphine ligand immobilized in a polyurea matrix.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/204489be324e4f329cfd20c17ea4f887 Zobrazit plný text záznamu View record in DOAJ