catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato]
| Autor: | Hai-Kang Guo, Feng Fu, Long Tang, Xiang-Yang Hou, Jia Cao |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 8, Pp m1078-m1078 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812031534 |
| Popis: | In the title compound, [Co(C14H8O5)(C12H8N2)]n, the CoII atom is six-coordinated in a distorted octahedral coordination geometry by four O atoms from two chelating carboxylate groups from different 2,4′-oxydibenzoate anions and by two N atoms from a 1,10-phenanthroline (phen) ligand. The two benzene rings of the 2,4′-oxydibenzoate ligand form a dihedral angle of 77.14 (16)°. Adjacent CoII atoms are bridged by 2,4′-oxydibenzoate anions to form a helical chain that propagates along the b-axis direction. Neighboring chains are further assembled by intermolecular π–π stacking interactions between inversion-related phen ligands [centroid-to-centroid distance = 4.0869 (8) Å] to form a two-dimensional supramolecular architecture. |
| Databáze: | Directory of Open Access Journals |
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