(μ-Piperazine-1,4-dicarbodithioato-κ4S1,S1′:S4,S4′)bis[bis(triphenylphosphane-κP)gold(I)] chloroform disolvate

Autor: Ilia A. Guzei, Lara C. Spencer, Stacy Lillywhite, James Darkwa
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 11, Pp m1629-m1630 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811044229
Popis: In the title compound, [Au2(C6H8N2S4)(C18H15P)4]·2CHCl3, the digold complex resides on a crystallographic inversion center and co-crystallizes with two molecules of chloroform solvent. The piperazine-1,4-dicarbodithioate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetrahedral punctuated by a very acute S—Au—S bite angle.
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