(μ-Piperazine-1,4-dicarbodithioato-κ4S1,S1′:S4,S4′)bis[bis(triphenylphosphane-κP)gold(I)] chloroform disolvate
| Autor: | Ilia A. Guzei, Lara C. Spencer, Stacy Lillywhite, James Darkwa |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 11, Pp m1629-m1630 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811044229 |
| Popis: | In the title compound, [Au2(C6H8N2S4)(C18H15P)4]·2CHCl3, the digold complex resides on a crystallographic inversion center and co-crystallizes with two molecules of chloroform solvent. The piperazine-1,4-dicarbodithioate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetrahedral punctuated by a very acute S—Au—S bite angle. |
| Databáze: | Directory of Open Access Journals |
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