4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions

Autor:	Jérôme Husson, Laurent Guyard
Jazyk:	angličtina
Rok vydání:	2018
Předmět:	oligopyridine furan derivatives N-ligands catalyst Inorganic chemistry QD146-197
Zdroj:	Molbank, Vol 2018, Iss 4, p M1032 (2018)
Druh dokumentu:	article
ISSN:	1422-8599
DOI:	10.3390/M1032
Popis:	The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by elemental analyses and HR-MS. Owing to its chelating properties, this new terpyridine molecule was tested as a ligand in a metal-catalyzed reaction: The Ni-catalyzed dimerization of benzyl bromide.
Databáze:	Directory of Open Access Journals
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