2-Fluoro-N-o-tolylbenzamide
| Autor: | Aamer Saeed, Rasheed Ahmad Khera, Shahid Ameen, Jim Simpson, Roderick G. Stanley |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 1, Pp o201-o201 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808043122 |
| Popis: | In the title compound, C14H12FNO, the ortho-F atom and corresponding H atom on the fluorobenzene ring are disordered over two positions with occupancies of 0.856 (4) and 0.144 (4). The amide unit is planar with a maximum deviation of 0.0057 (16) Å and the amide plane makes dihedral angles of 38.27 (11)° with the fluorobenzene ring plane and 37.53 (10)° with the tolyl ring. The two benzene rings are inclined at an angle of 4.17 (15)°. In the crystal structure, chains form along b through N—H...O hydrogen bonds augmented by C—H...π interactions. Additional intermolecular C—H...O and C—H...F hydrogen bonds further stabilize the structure, forming layers in the ac plane. |
| Databáze: | Directory of Open Access Journals |
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