Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds

Autor: Chengyao Kimmy Cao, Evgeny Tretyakov, Chao Chen
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Green Synthesis and Catalysis, Vol 2, Iss 1, Pp 62-65 (2021)
Druh dokumentu: article
ISSN: 2666-5549
DOI: 10.1016/j.gresc.2020.12.001
Popis: An efficient procedure to access to ortho-SCF3 substituted benzophenones from arynes and trifluoromethylthioesters has been developed under transition-metal free conditions. This difunctionalization process involves the first insertion of arynes into the C–S σ-bonds to achieve vicinal trifluoromethylthiolation-acylation of arenes in one step.
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