| Autor: |
Amulya Raj, Cedric Samuel, Kalappa Prashantha |
| Jazyk: |
angličtina |
| Rok vydání: |
2020 |
| Předmět: |
|
| Zdroj: |
Frontiers in Materials, Vol 7 (2020) |
| Druh dokumentu: |
article |
| ISSN: |
2296-8016 |
| DOI: |
10.3389/fmats.2020.00193 |
| Popis: |
Engineering properties of partially-biobased poly(L-Lactide)/poly(amide-12) (PLA/PA12) blends are here addressed using a functional compatibilizer, namely poly(L-Lactide) grafted maleic anhydride (PLA-g-MA). PLA/PA12 blends with compatibilizers are processed using twin-screw extrusion, and the amount of PLA-g-PMA is here optimized with respect to final blend properties such as ductility, impact toughness, and thermal resistance. Blend morphologies depict the enhanced PA12 dispersion into PLA-g-MA with strong interfacial adhesion, in accordance with a compatibilization effect of PLA-g-MA in PLA/PA12 blends. Ductility of the compatibilized blends shows remarkable improvements with the highest ductility close to 290% for an optimized PLA/PA12/PLA-g-MA weight composition (respectively, 69/30/1). The impact strength of compatibilized blends showed a similar two-fold improvement for compatibilized blends. Morphology of injection molded samples revealed finer dispersion and stronger interfaces. The morphology of the transversal section displayed fibrillation of PA12 for PLA-g-MA content up to 2 wt.%. Fibrillation and lower droplet size seemed to play a key role in the improvement of ductility in compatibilized blends. Considerable synergy was detected in the dynamic mechanic analysis of the compatibilized blends. The thermal resistance of the PLA/PA12 blends showed improvement, and this behavior could be due to the formation of copolymer leading to additional interfacial crystallization. This study consequently indicates that PLA-g-MA is an efficient compatibilizer for partially biobased PLA/PA12 blends with potential applications in the automotive and electronic industry. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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