Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules

Autor: Yoshiaki Shoji, Naoki Tanaka, Sho Muranaka, Naoki Shigeno, Haruka Sugiyama, Kumiko Takenouchi, Fatin Hajjaj, Takanori Fukushima
Jazyk: angličtina
Rok vydání: 2016
Předmět:
Zdroj: Nature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/ncomms12704
Popis: Coupling reactions to form C–C bonds typically require transition metals. Here the authors report that an organoboron compound can allow sequential alkyne insertion and unusual oxidative deborylation/Csp2 –Csp2 coupling, enabling the transformation of acetylenes into extended π-conjugated molecules.
Databáze: Directory of Open Access Journals