One-step hydrothermal synthesis and electrocatalytic performance of MoS2/RGO composites

Autor: ZHANG Chuan-xiang, CHEN Ya-ling, GONG Yun, LIU Hui-ying, DAI Yu-ming, CONG Yuan
Jazyk: čínština
Rok vydání: 2020
Předmět:
Zdroj: Cailiao gongcheng, Vol 48, Iss 5, Pp 56-61 (2020)
Druh dokumentu: article
ISSN: 1001-4381
DOI: 10.11868/j.issn.1001-4381.2018.001129
Popis: Molybdenum disulfide/reduced graphene(MoS2/RGO) composite catalyst was synthesized by one-step hydrothermal method in order to improve the catalytic activity and stability. X-ray diffractometer, scanning electron microscope, transmission electron microscope and rotating disk electrode were used to characterize the physical and chemical properties of the catalyst. The results show that the molybdenum disulfide compound with graphene has pear-shaped structure with few layers, and the layer spacing increases which is uniformly attached to the thin layer of graphene. The oxygen reduction process of molybdenum disulfide catalyst is mainly carried out in two-electron path, while MoS2/RGO composite catalyst can play a synergistic catalytic role in oxygen reduction process and the average number of electron transfer in the process is 3.58. The current density retention rate of the composite catalyst after 20000 s is up to 89.7%.
Databáze: Directory of Open Access Journals