Effect of Metal-Ligand Coordination Complexes on Molecular Dynamics and Structure of Cross-Linked Poly(dimethylosiloxane)
| Autor: | Angelika Wrzesińska, Izabela Bobowska, Paulina Maczugowska, Joanna Małolepsza, Katarzyna M. Błażewska, Aleksandra Wypych-Puszkarz |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | Polymers, Vol 12, Iss 8, p 1680 (2020) |
| Druh dokumentu: | article |
| ISSN: | 2073-4360 49043447 |
| DOI: | 10.3390/polym12081680 |
| Popis: | Poly(dimethylosiloxane) (PDMS) cross-linked by metal-ligand coordination has a potential functionality for electronic devices applications. In this work, the molecular dynamics of bipyridine (bpy)–PDMS-MeCl2 (Me: Mn2+, Fe2+, Ni2+, and Zn2+) are investigated by means of broadband dielectric spectroscopy and supported by differential scanning calorimetry and density functional theory calculations. The study of molecular motions covered a broad range of temperatures and frequencies and was performed for the first time for metal-ligand cross-linked PDMS. It was found that the incorporation of bpy moieties into PDMS chain prevents its crystallization. The dielectric permittivity of studied organometallic systems was elevated and almost two times higher (ε′ ~4 at 1 MHz) than in neat PDMS. BpyPDMS-MeCl2 complexes exhibit slightly higher glass transition temperature and fragility as compared to a neat PDMS. Two segmental type relaxations (α and αac) were observed in dielectric studies, and their origin was discussed in relation to the molecular structure of investigated complexes. The αac relaxation was observed for the first time in amorphous metal-ligand complexes. It originates from the lower mobility of PDMS polymer chains, which are immobilized by metal-ligand coordination centers via bipyridine moieties. |
| Databáze: | Directory of Open Access Journals |
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