Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate
| Autor: | Tapashi G. Roy, Saroj K. S. Hazari, Kanak K. Barua, Seik Weng Ng, Edward R. T. Tiekink |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 12, Pp m1722-m1723 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811046484 |
| Popis: | The CoIII atom in the title complex, [CoCl2(C40H48N4)]ClO4, is octahedrally coordinated within a trans-Cl2N4 donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N—H atoms, which are orientated to one side of the N4 plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C—H...O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4). |
| Databáze: | Directory of Open Access Journals |
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