A STUDY INTO THE FORMATION PROCESSES OF URANIUM NANAOCLUSTERS WITH VARIABLE VALENCE WHILE URANYL SOLUTIONS WITH DIMETHYL FORMAMIDE ARE SUBJECTED TO IRRADIATION AND DEPOSITED ON GLASS SURFACE

Autor: А.P. Zajogin, D.S. Umreiko, А.I. Komyak, J.I. Buloichik, S.D. Umreiko
Jazyk: ruština
Rok vydání: 2012
Předmět:
Zdroj: Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов, Iss 4, Pp 103-107 (2012)
Druh dokumentu: article
ISSN: 2226-4442
2658-4360
Popis: Using the methods of electronic and IR absorption, we have studied the photochemical formation processes of the complexes between tri-, tetra-, and pentavalent uranium and organic ligands when the solutions of UO2(NO3)3*6H2O in dimethyl formamide, UO2(NO3)3*6H2O in dimethyl formamide with the addition of CCl4, and UO2(ClO4)3*5H2O in dimethyl formamide were subjected to the effect of light-diode radiation (430-450 nm). The possibility for deposition of the complexes of tetra- and pentavalent uranium on the glass surface was established.
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