Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium]
| Autor: | Xiu-Zhi Xu, Zhu-Lai Li, Wen-Jin Yan, Hui-Li Chi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 2, Pp m190-m190 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811000535 |
| Popis: | The title coordination polymer, [CdBr2(C8H8N4)2]n, arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CdBr2N4 octahedral arrangement. The bridging 1-(4-pyridylmethyl)-1H-1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 44 sheet structure in the crystal. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|