1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate
| Autor: | Samuel Johnson, Ghezai T. Musie, Edward R. T. Tiekink |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 1, Pp o64-o65 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809051824 |
| Popis: | In the title salt hydrate, C22H30N2O62+·2Cl−·CH4O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H...Cl−, N+—H...Cl− and N+—H...O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C—H...O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C—H...π contacts. |
| Databáze: | Directory of Open Access Journals |
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