A Nickel/Organoboron-Catalyzed Coupling of Aryl Bromides with Sodium Sulfinates: The Synthesis of Sulfones under Visible Light

Autor:	Siyi Ding, Weina Tian, Qiaohuan Lv, Zongcheng Miao, Liang Xu
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	sulfone compounds sodium sulfinates dually catalytic system organoboron photocatalyst Organic chemistry QD241-441
Zdroj:	Molecules, Vol 29, Iss 14, p 3418 (2024)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules29143418
Popis:	An efficient cross-coupling of aryl bromides with sodium sulfinates, using an organoboron photocatalyst with nickel, is described herein. Under the irradiation of white light, this dually catalytic system enables the synthesis of a series of sulfone compounds in moderate to good yields. A broad range of functional groups and heteroaromatic compounds is tolerated under these reaction conditions. The use of an organoboron photocatalyst highlights a sustainable alternative to iridium or ruthenium complexes. These findings contribute to the field of photochemistry and provide a greener approach to sulfone synthesis.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/e1b35de3af364ccea91d4d6b59a8b17f Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.