(μ-4,4′-Bipyridine-κ2N:N′)bis[bis(N,N-dimethyldithiocarbamato-κ2S,S′)zinc(II)]

Autor: Mei-Qin Zha, Xing Li, Yue Bing, Yue Lu
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 11, Pp m1465-m1465 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536810042650
Popis: The title dinuclear ZnII complex, [Zn2(C3H6NS2)4(C10H8N2)], is centrosymmetric; the mid-point of the C—C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the ZnII cation, which is also chelated by two dimethyldithiocarbamate anions, giving a trigonal-bipyramidal ZnNS4 geometry. Weak intermolecular C—H...S hydrogen bonding is present in the crystal structure.
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