N-Salicylideneamine Derivatives with TEMPO Substituents

Autor: Shin’ichi Nakatsuji, Jun-ichi Yamada, Hiroki Akutsu, Masayuki Hata
Jazyk: angličtina
Rok vydání: 2004
Předmět:
Zdroj: Molecules, Vol 9, Iss 9, Pp 746-756 (2004)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/90900746
Popis: Three N-salicylideneamine derivatives bearing TEMPO (2,2,6,6-tetra- methyl-1-piperidinyloxy) substituents were prepared in order to study their structure and property relationships and to investigate the possibilities of the existence of heat and/or light responsive magnetic properties. Curie-Weiss behavior with weak ferromagnetic intermolecular spin-spin interactions was observed in one of the radicals, while antiferromagnetic interactions were predominant for the other radicals and the structure-property relationships were investigated for the radical compounds from their crystal structures obtained by X-ray analyses. Preliminary results of the examination of their responses towards light and heat are also described.
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