Autor: |
Hossam A. Nabwey, Maha A. Tony |
Jazyk: |
angličtina |
Rok vydání: |
2024 |
Předmět: |
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Zdroj: |
Scientific Reports, Vol 14, Iss 1, Pp 1-17 (2024) |
Druh dokumentu: |
article |
ISSN: |
2045-2322 |
DOI: |
10.1038/s41598-024-78678-8 |
Popis: |
Abstract The current study investigating the preparation and application of a Multiferroic nano-scale silver zinc ferrite substance (Ag0.5Zn0.5Fe2O4 nanocatalyst) has been established. Multiferroic silver zinc ferrite substance is prepared by co-precipitation technique as hybridized composite. This synethsized nanoparticles was characterized via X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) as well as Scanning Electron Miscospopy (SEM). Such nanoparticles are used as a sustainable recyclable photo-Fenton’s reagent precursor for treating insecticide in wastewater. The results revealed a high Acinate oxidation rate reached to 97% removal within 40 min of irradiance time. To increase the performance, the operating variables are optimized. pH 3.0 and 40 and 400 mg/L for Ag0.5Zn0.5Fe2O4 and hydrogen peroxide, respectively are identified as the optimum values. Also, kinetics and thermodynamic are evaluated and the reaction is subsequent the first-order kinetics model and exothermic and non-spontaneous in nature with a low energy barrier of 35.02 kJ/mol. The advantage of Ag0.5Zn0.5Fe2O4 catalyst is its sustainability since it recovered for multiple reuse with a high activity reached to 80% removal rate after six cyclic use compared to 97% of fresh catalyst use. |
Databáze: |
Directory of Open Access Journals |
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