Recent Studies of (+)-3-Carene Transformations with the Retention of the Native Framework

Autor: Serghei Curlat
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 14, Iss 2, Pp 32-555 (2019)
Druh dokumentu: article
ISSN: 1857-1727
2345-1688
DOI: 10.19261/cjm.2019.616
Popis: This review presents last decade and some past especially relevant studies in the field of (+)-3-carene synthetic transformations. This paper discusses exclusively the transformations of (+)-3-carene, proceeding with the retention of the native bicyclic carbon skeleton. The data concerning the features of epoxidation and oxidation reactions of (+)-3-carene, the synthesis of sulphur- and selenium-containing derivatives and their use in asymmetric synthesis are given. It also describes methods for producing amino derivatives of (+)-3-carene, substituted heterocycles based on it, reactions for the preparation of aziridines, azido-alcohols and azidoamines, as well as chiral phosphites as bidentate ligands.
Databáze: Directory of Open Access Journals