Crystal structure of (4-fluorophenyl-κC1)iodido(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)palladium(II)

Autor:	Jin-Jin Yan, Chang-Ge Zheng
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	crystal structure palladium(II) complex tetramethylethylenediamine square-planar coordination single-crystal X-ray study hydrogen bonding Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 5, Pp m124-m125 (2015)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989015008014
Popis:	In the title compound, [Pd(C6H4F)I(C6H16N2)], the PdII atom is coordinated by two N atoms from the N,N,N′,N′-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the PdII atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H...F and C—H...I hydrogen bonds link the molecules into sheets in the bc plane.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/191051f8fbf445c5bbfb192b32fc096e Zobrazit plný text záznamu View record in DOAJ