Complete Assignments of NMR Spectral Data of Three C19-Diterpenoid Alkaloids

Autor: YIN Tian-peng, WANG Ya-rong, WANG Min, SHI Wen-zhi, ZHANG Zheng-qian, HE Sha-sha
Jazyk: čínština
Rok vydání: 2019
Předmět:
Zdroj: Chinese Journal of Magnetic Resonance, Vol 36, Iss 3, Pp 331-340 (2019)
Druh dokumentu: article
ISSN: 20182694
1000-4556
DOI: 10.11938/cjmr20182694
Popis: C19-diterpenoid alkaloids have complex and diverse structures, posing great challenges for nuclear magnetic resonance (NMR)-based structural elucidation. Three C19-diterpenoid alkaloids, including taronenine E (1), chasmaconitine (2) and vilmorisine (3), were isolated from the roots of Aconitum taronense Fletcher et Lauener, and analyzed by various NMR spectroscopy methods (i.e., 1H and 13C NMR, DEPT, 1H-1H COSY, HSQC and HMBC). Complete assignments of the NMR chemical shifts were obtained, providing a good reference for the further research of C19-diterpenoid alkaloids.
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