cis,trans,cis,cis-7-tert-Butyldimethylsilyloxy-4,10-dimethyltetracyclo[5.4.1.04,12.010,12]dodecan-2-one
| Autor: | Philipp Weyermann, Reinhart Keese, Helen Stoeckli-Evans |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 2, Pp o340-o340 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810000887 |
| Popis: | In the structure of the title compound, C20H34O2Si, a cis,trans,cis,cis-[4.5.5.5]fenestrane derivative, the geometry of the central C(C)4 substructure shows considerable distortion from an ideal tetrahedral arrangement towards planarity, with two opposite bridgehead bond angles of 128.87 (18) and 122.83 (17)°. The other bridgehead angle of the trans-bicyclo[3.3.0]octane subunit is also large [126.57 (19)°]. |
| Databáze: | Directory of Open Access Journals |
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