Efficient catalytic performance of Ru nanoparticles for hydrogen generation from NH3BH3: The dual role of Mo oxide

Autor: Xigang Du, Hongyu Liu, Mengfan Su, Yuping Tai, Bingli Pan, Ning Guo, Jun Zhang
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Catalysis Communications, Vol 175, Iss , Pp 106616- (2023)
Druh dokumentu: article
ISSN: 1873-3905
DOI: 10.1016/j.catcom.2023.106616
Popis: Ru nanoparticles doped and supported by Mo oxide (Ru/Mo oxide NPs) were synthesized via an in situ co-precipitation strategy for hydrogen production via hydrolysis of ammonia borane (AB). The optimized Ru0.9Mo0.1 catalyst composition exhibited a total turnover frequency (TOF) value of 514.8 molH2 (molRu0.9Mo0.1)−1 min−1 at room temperature. Systematic characterization of the catalysts unveiled the dual role of Mo oxide in regulating the structure and catalytic performance of Ru NPs. This work provides a new approach for the design of Ru-based nanocatalysts toward hydrolysis of AB for H2 harvest.
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