XPS Investigation of Magnetization Reduction Behavior and Kinetics of Oolitic Hematite in Gas-Based Roasting

Autor: Mengfei Li, Hanquan Zhang, Fan Yang, Tiejun Chen, Manman Lu, Hong Yu
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Minerals, Vol 14, Iss 5, p 462 (2024)
Druh dokumentu: article
ISSN: 2075-163X
DOI: 10.3390/min14050462
Popis: Magnetization reduction roasting is an important method for the utilization of oolitic magnetite. In this study, the magnetization reduction behavior and kinetics of oolitic hematite in gas-based roasting were systematically investigated by X-ray photoelectron spectroscopy (XPS). The results revealed that under optimal roasting conditions of 650 °C, a roasting time of 60 min, and a CO concentration of 30%, the magnetization reduction rate of the roasted product reached 44.34%. Furthermore, the weak magnetic separation concentrate presented a TFe of 58.09% and a concentrate iron recovery of 94.3%. The results of the XPS spectrum indicated that the peak area ratio (Fe2+/Fe3+) gradually increased with an increase in roasting temperature, roasting time, and CO concentration, while over-reduction occurred when the roasting temperature exceeded 750 °C. The investigation of magnetization roasting kinetics for varying particle sizes demonstrated that the magnetization reduction process is controlled by chemical reaction, with a corresponding activation energy range of 42.96 kJ/mol to 63.29 kJ/mol, indicating the particle size has little effect on the magnetization reduction of oolitic hematite.
Databáze: Directory of Open Access Journals
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