Influence of the synthesis conditions on the characteristics and metal adsorption properties of the 3-(1,4-phenylenediamine)propylsilica xerogel

Autor: J. C. P. Vaghetti, J. L. Brasil, T. M. H. Costa, E. C. Lima, E. V. Benvenutti
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Eclética Química, Vol 30, Iss 4, Pp 43-49 (2018)
Druh dokumentu: article
ISSN: 1678-4618
DOI: 10.26850/1678-4618eqj.v30.4.2005.p43-49
Popis: The hybrid 3-(1,4-phenylenediamine)propylsilica xerogel was obtained starting from two different organic precursor quantity (5 and 8 mmol) to 22 mmol of TEOS, in the synthesis. The xerogel samples were characterized by using CHN elemental analysis, N 2 adsorption-desorption isotherms, infrared thermal analysis. The xerogel was used as metal sorbent for Cu 2+ , Cd 2+ and Pb 2+ in aqueous solution with concentration range of 10 -3 to 10 -5 mmol l -1 . The quantity of organic precursor added in the synthesis influences the characteristics of the xerogel as morphology and thermal stability, as well as the metal adsorption capacity.
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