| Autor: |
Kai-Stephan Feichtner, Viktoria H. Gessner |
| Jazyk: |
angličtina |
| Rok vydání: |
2016 |
| Předmět: |
|
| Zdroj: |
Inorganics, Vol 4, Iss 4, p 40 (2016) |
| Druh dokumentu: |
article |
| ISSN: |
2304-6740 |
| DOI: |
10.3390/inorganics4040040 |
| Popis: |
The synthesis of [H2C(PPh2=NSiMe3)(SO2Ph)] (1) and its mono- and dimetalation are reported. Due to the strong anion-stabilizing abilities of the iminophosphoryl and the sulfonyl group monometalation to 1-K and dimetalation to 1-Li2 proceed smoothly with potassium hydride and methyllithium, respectively. Both compounds could be isolated in high yields and were characterized by NMR spectroscopy as well as XRD analysis. The methanide 1-K forms a coordination polymer in the solid state, while in case of the methandiide a tetrameric structure is observed. The latter features an unusual structural motif consisting of two (SO2Li)2 eight-membered rings, which are connected with each other via the methandiide carbon atoms and additional lithium atoms. With increasing metalation a contraction of the P–C–S linkage is observed, which is well in line with the increased charge at the central carbon atom and involved electrostatic interactions. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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