PVP-Stabilized Palladium Nanoparticles in Silica as Effective Catalysts for Hydrogenation Reactions
Autor: | Caroline Pires Ruas, Daiane Kessler Fischer, Marcos Alexandre Gelesky |
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Jazyk: | angličtina |
Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Journal of Nanotechnology, Vol 2013 (2013) |
Druh dokumentu: | article |
ISSN: | 1687-9503 1687-9511 |
DOI: | 10.1155/2013/906740 |
Popis: | Palladium nanoparticles stabilized by poly (N-vinyl-2-pyrrolidone) (PVP) can be synthesized by corresponding Pd(acac)2 (acac = acetylacetonate) as precursor in methanol at 80°C for 2 h followed by reduction with NaBH4 and immobilized onto SiO2 prepared by sol-gel process under acidic conditions (HF or HCl). The PVP/Pd molar ratio is set to 6. The effect of the sol-gel catalyst on the silica morphology and texture and on Pd(0) content was investigated. The catalysts prepared (ca. 2% Pd(0)/SiO2/HF and ca. 0,3% Pd(0)/SiO2/HCl) were characterized by TEM, FAAS, and SEM-EDS. Palladium nanoparticles supported in silica with a size 6.6 ± 1.4 nm were obtained. The catalytic activity was tested in hydrogenation of alkenes. |
Databáze: | Directory of Open Access Journals |
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