Carbothermal reduction kinetics of mechanically activated chromite with graphite

Autor: Kenan Yıldız
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Vol 15, Iss 1 (2011)
Druh dokumentu: article
ISSN: 1301-4048
2147-835X
DOI: 10.5505/süfbed.v15i1.5000011816
Popis: The carbothermal reduction kinetics of mechanically activated chromite with graphite under an argon atmosphere was investigated at temperatures between 1100 and 1400°C. Zhuravlev-Lesokhin-Tempelman (ZLT) method was used in the reduction kinetics for non-activated chromite and the activation energy was calculated as 401.7 kJ/mol. Solid-state diffusion method was used in the reduction kinetics for 60 min-activated chromite and the activation energy was calculated as 283.3 kJ/mol. This decrease in activation energy was due to structural disordering in chromite structure by mechanical activation.
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