Tris[4-bromo-2-(methyliminomethyl)phenolato-κ2N,O]cobalt(III)

Autor: Qiu-Ping Huang, Chun-Lian Zhang, Ru-Xia Zhao, Li Yang, Xi-Fu Jiang
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 69, Iss 11, Pp m601-m601 (2013)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536813027591
Popis: In the title compound, [Co(C8H7BrNO)3], the CoIII ion is coordinated in a slightly distorted octahedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyliminomethyl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, molecules are linked by pairs of weak C—H...Br hydrogen bonds, forming inversion dimers.
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