Investigations of the Thermal Parameters of Hybrid Sol–Gel Coatings Using Nondestructive Photothermal Techniques

Autor: Łukasz Chrobak, Dorota Korte, Hanna Budasheva, Mirosław Maliński, Peter Rodič, Ingrid Milošev, Sylwia Janta-Lipińska
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Energies, Vol 15, Iss 11, p 4122 (2022)
Druh dokumentu: article
ISSN: 1996-1073
DOI: 10.3390/en15114122
Popis: This article presents the results of comparative investigations of thermal parameters of hybrid sol–gel coatings (named TMZ) prepared from tetraethyl orthosilicate and organically modified 3-methacryloxypropyltrimethoxysilane. The coatings were prepared with the addition of zirconium(IV) tetrapropoxide chelated with methacrylic acid. Two series of samples were investigated: the first series, TMZ-I, TMZ-II and TMZ-III, with different amounts of zirconium, and the second series, TMZ-I/Ce, TMZ-II/Ce and TMZ-III/Ce, with the addition of cerium nitrate. The influence of the amount of zirconium and cerium on the thermal parameters of the sol–gel coatings was next analyzed. Two non-destructive and photothermal techniques were used for this purpose: photothermal radiometry (PTR) and beam deflection spectroscopy (BDS). The thermal diffusivity and conductivity of the coatings were extracted from the frequency experiments and are presented and discussed. The two-layer model was applied to interpret the photothermal spectra. The results obtained using these two techniques are compared and discussed.
Databáze: Directory of Open Access Journals
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