Crystal structure of bis[N,N-bis(2-hydroxyethyl)glycinato-κ3O1,N,O2]cobalt(II) monohydrate
| Autor: | Yang Liu, Dan Zhou, Hai-Hui Liu, Chen-Cong He |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 11, Pp m199-m200 (2015) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S205698901501943X |
| Popis: | The title compound, [Co(C6H12O4)2]·H2O, was prepared by mild heating of an aqueous solution. The CoII ion has a slightly distorted octahedral coordination environment which is defined by two N atoms occupying the apical position, while the equatorial plane is furnished by two hydroxy O atoms and two carboxylate O atoms. The four hydroxy O atoms from two distinct N,N-bis(2-hydroxyethyl)glycine (bicH2−) ligands act as hydrogen-bond donors with two carboxylate O atoms as acceptors to form O—H...O hydrogen-bonded layers extending parallel to (100). In addition, the guest water molecule acts as both a hydrogen-bond donor and acceptor, so that each Co(bicH2)2 molecule is connected simultaneously to six neighbouring Co(bicH2)2 and two guest water molecules by hydrogen bonding. |
| Databáze: | Directory of Open Access Journals |
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