Phase Equilibria in Ternary System CsBr-AgBr-InBr3

Autor: Rustam K. Kamilov, Jahongir Z. Yuldoshev, Alexander V. Knotko, Anastasia V. Grigorieva
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Materials, Vol 16, Iss 2, p 559 (2023)
Druh dokumentu: article
ISSN: 1996-1944
DOI: 10.3390/ma16020559
Popis: The double perovskite halides A2BIBIIIX6 provide flexibility for various formulation adjustments and are of less toxicity in comparison with well-discussed complex lead halide derivatives. Such type of structure can be formed by replacing two Pb2+ ions in the cubic lattice with a pair of non-toxic heterovalent (monovalent and trivalent) metal cations, such as silver and indium. The aim of this work is to briefly characterize the phase equilibria in the ternary system CsBr-AgBr-InBr3 and investigate the thermodynamic availability of synthesis of Cs2AgInBr6 double perovskite phase by solid-state sintering or melt crystallization. The results demonstrate the unfeasibility of the Cs2AgInBr6 phase but high stability of the corresponding binary bromides perspective for optoelectronics.
Databáze: Directory of Open Access Journals
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