Efeito da composição das correntes do conversor das unidades de FCC no desempenho catalítico de aditivos DESOx Influence of the composition of the streams to the FCC converter unit on the catalytic performance of DESOx additives

Autor: Carla Maria Salerno Polato, José Luiz Fontes Monteiro, Cristiane Assumpção Henriques
Jazyk: English<br />Spanish; Castilian<br />Portuguese
Rok vydání: 2009
Předmět:
Zdroj: Química Nova, Vol 32, Iss 1, Pp 38-44 (2009)
Druh dokumentu: article
ISSN: 0100-4042
1678-7064
DOI: 10.1590/S0100-40422009000100007
Popis: Hydrotalcite-like compounds having Mg partially replaced by Cu or Mn were prepared and used as precursors for two mixed oxides (Cu-OM50 and Mn-OM50) that were evaluated for SOx removal in the presence of O2, NO and CO. Under SO2/O2 reaction system, SOx removal was slightly higher over Cu-OM50. The addition of CO and NO to the feed markedly hindered the SO2 oxidation over Cu-OM50 while no significant effect was observed for Mn-OM50. For the regeneration step, the use of propane instead of H2 reduces regeneration capacity, mainly for Cu-OM50. Mn-OM50 was less affected by the feed composition, suggesting that it was a promising additive for SOx removal.
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