Modification of Graphite Sheet Anode with Iron (II, III) Oxide-Carbon Dots for Enhancing the Performance of Microbial Fuel Cell

Autor: Babita Tripathi, Soumya Pandit, Aparna Sharma, Sunil Chauhan, Abhilasha Singh Mathuriya, Pritam Kumar Dikshit, Piyush Kumar Gupta, Ram Chandra Singh, Mohit Sahni, Kumud Pant, Satyendra Singh
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Catalysts, Vol 12, Iss 9, p 1040 (2022)
Druh dokumentu: article
ISSN: 2073-4344
DOI: 10.3390/catal12091040
Popis: The present study explores the use of carbon dots coated with Iron (II, III) oxide (Fe3O4) for its application as an anode in microbial fuel cells (MFC). Fe3O4@PSA-C was synthesized using a hydrothermal-assisted probe sonication method. Nanoparticles were characterized with XRD, SEM, FTIR, and RAMAN Spectroscopy. Different concentrations of Fe3O4- carbon dots (0.25, 0.5, 0.75, and 1 mg/cm2) were coated onto the graphite sheets (Fe3O4@PSA-C), and their performance in MFC was evaluated. Cyclic voltammetry (CV) of Fe3O4@PSA-C (1 mg/cm2) modified anode indicated oxidation peaks at −0.26 mV and +0.16 mV, respectively, with peak currents of 7.7 mA and 8.1 mA. The fluxes of these anodes were much higher than those of other low-concentration Fe3O4@PSA-C modified anodes and the bare graphite sheet anode. The maximum power density (Pmax) was observed in MFC with a 1 mg/cm2 concentration of Fe3O4@PSA-C was 440.01 mW/m2, 1.54 times higher than MFCs using bare graphite sheet anode (285.01 mW/m2). The elevated interaction area of carbon dots permits pervasive Fe3O4 crystallization providing enhanced cell attachment capability of the anode, boosting the biocompatibility of Fe3O4@PSA-C. This significantly improved the performance of the MFC, making Fe3O4@PSA-C modified graphite sheets a good choice as an anode for its application in MFC.
Databáze: Directory of Open Access Journals
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