Increase in properties of copper electrical contacts in formation of composite coatings based on Ni–C–Ag–N system

Autor: Denis Anatolevich Romanov, Vasilii Vitalievich Pochetukha, Kirill Valerievich Sosnin, Stanislav Vladimirovich Moskovskii, Victor Evgenyevich Gromov, Vladimir Andreevich Bataev, Yuri Fedorovich Ivanov, Alexander Petrovich Semin
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 19, Iss , Pp 947-966 (2022)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2022.05.040
Popis: The article is concerned with analyzing the structure and properties of the Ni–C–Ag–N coating formed on copper by the complex method combining the electroexplosive spraying of coating, its irradiation by a pulsed electron beam and a subsequent nitriding in plasma of a gas discharge of low pressure. The structural constituents of coating's surface after the electroexplosive spraying as well as after the electron-beam processing and nitriding are studied. It is shown that a coating's thickness amounts to ≈90 μm. The wear resistance of a copper sample with the deposited coating exceeds that of the copper without the coating by ≈ 1.6 times. The friction coefficient of samples with the coating (μ = 0.5) is less than that of the copper without the coating (μ = 0.679) by ≈ 1.35 times. It is established that the hardness of the coating increases as the substrate is approached and reaches the maximum value of ≈1780 MPa (the hardness of substrate is 1300 MPa). By means of micro-X-ray-spectral analysis it is detected that the main chemical element of the coating is silver, but copper, nickel, carbon and nitrogen are present in a considerably smaller quantity. It is established by the methods of diffraction electron microscopy that the main phases of the coating are solid solutions.
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