Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
| Autor: | Shuang-Ming Meng, Hai Xie, Yue-Qin Fan, Yong Guo |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 11, Pp m1363-m1363 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808031589 |
| Popis: | In the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thiocyanate anion and the O atom of the methanol molecule. In the crystal structure, complex molecules are linked by an intermolecular O—H...S hydrogen bond, forming a chain running along [101]. |
| Databáze: | Directory of Open Access Journals |
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