| Autor: |
Hiroshi Abe, Hiroaki Kishimura |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Journal of Ionic Liquids, Vol 2, Iss 1, Pp 100018- (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2772-4220 |
| DOI: |
10.1016/j.jil.2022.100018 |
| Popis: |
X-ray reflectivity (XRR) examined surface structures of hydrophobic quaternary ammonium ionic liquids, and their propanol mixtures were examined by XRR. The quaternary ammonium cations were [N(n)111]+ (n = 3, 4, and 6) and an anion was commonly bis(trifluoromethanesulfonyl)imide, [TFSI]−. The surface tension of pure [N(n)111][TFSI] increased with increasing n. Pure [N(n)111][TFSI] surface structures were stable in all gas atmospheres. The XRR of [N3111][TFSI]-1-propanol equilibrated showed CO2-induced surface roughness. Time-resolved XRR under CO2 of [N(n)111][TFSI]-propanol provided surface instabilities and a reconstruction process. The addition of 2-propanol to CO2 in [N4111][TFSI] promoted specific surface layering and a large amount of CO2 capture. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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