| Autor: |
Eugenia V. Peresypkina, Anatolie Gavriluta, Kira E. Vostrikova |
| Jazyk: |
angličtina |
| Rok vydání: |
2016 |
| Předmět: |
|
| Zdroj: |
Crystals, Vol 6, Iss 9, p 102 (2016) |
| Druh dokumentu: |
article |
| ISSN: |
2073-4352 |
| DOI: |
10.3390/cryst6090102 |
| Popis: |
The ligand exchange in (n-Bu4N)2OsIVCl6 (n-Bu4N = tetra-n-butylammonium) leads to the formation of the osmium(IV) heptacyanide, the first fully inorganic homoleptic complex of heptacoordinated osmium. The single-crystal X-ray diffraction (SC-XRD) study reveals the pentagonal bipyramidal molecular structure of the [Os(CN)7]3− anion. The latter being a diamagnetic analogue of the highly anisotropic paramagnetic synthon, [ReIV(CN)7]3− can be used for the synthesis of the model heterometallic coordination compounds for the detailed study and simulation of the magnetic properties of the low-dimensional molecular nanomagnets involving 5d metal heptacyanides. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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